Within UKCA, N2O5 hydrolysis
N2O5 + H2O --> HONO2 + HONO2
is actually covered by 2 separate reactions, H04 and B85. There is actually considerable overlap of these reactions in the troposphere, leading to overcounting.
A fix is to ensure, using the tropospheric mask, that only H04 works in the stratosphere and B85 only works in the troposphere.
This will be controlled with a temporary logical and changes are required to the UM (MetOffice/um#61) and UKCA to account for this, along with new STASH output to be able to check that the logic is working as intended.