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CP.bib
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25 lines (25 loc) · 1.46 KB
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@article{ 14RaBrWe.CP,
Author = {Ram, R. S. and Brooke, J. S. A. and Western, C. M. and Bernath, P. F.},
Title = {{Einstein A-values and oscillator strengths of the A(2)Pi-X-2 Sigma(+)
system of CP}},
Journal = JQSRT,
Year = {{2014}},
Volume = {{138}},
Pages = {107-115},
Abstract = {{Line strengths for bands of the A(2)Pi-X-2 Sigma(+) transition of CP,
including the effect of rotation on the vibrational wavefunctions (the
Herman-Wallis effect), have been calculated using Western's PGOPHER
program and Le Roy's LEVEL program. The potential energy functions for
the A(2)Pi and X-2 Sigma(+) state were computed using spectroscopic
constants obtained from high resolution spectra. The RKR potentials of
the two states, and the electronic transition dipole moments of this
transition calculated in a recent ab initio study have been used in Le
Roy's LEVEL program to produce transition dipole moment matrix elements.
The matrix elements have been converted from Hund's case (b) to (a), and
then used in PGOPHER to generate a line list containing observed and
calculated wavenumbers, Einstein A coefficients and f-values for 75
bands with v=0-8 for both states. The Einstein A coefficients have been
used to compute radiative lifetimes for v=0-5 in the A(2)Pi state. The
line list may be useful for computing the molecular opacities of CP
needed to simulate the spectra of stellar and substellar sources}},
DOI = {10.1016/j.jqsrt.2014.01.030}}