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CoH.bib
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@article{ 06GoRoBe.CoH,
Author = {Gordon, I E and Le Roy, R J and Bernath, P F},
Title = {Near infrared emission spectra of CoH and CoD},
Journal = JMS,
Year = {2006},
Volume = {237},
Pages = {11-18},
Abstract = {New high resolution emission spectra of CoH and CoD molecules have been
recorded in the 640 run to 3.5 mu m region using a Fourier transform
spectrometer. The bands were excited in a carbon tube furnace by the
reaction of cobalt metal vapor and a mixture of H-2 or D-2 With He at a
temperature of about 2600 degrees C. Eight bands were observed for the
A(t3)Phi(4)-X-3 Phi(4) electronic transition of CoD, and five bands for
the corresponding transition of CoH. The (0,0) bands of the
A(t3)Phi(3)-X-3 Phi(3) system Were also recorded for both isotopologues,
although one of the parity components in the X-3 Phi(3) sub-state of CoH
was found to be perturbed. The A(t3)Phi(3)-X-3 Phi(4) transition was
also observed in our spectrum of CoH. In addition, a new {[}13.3]4
electronic state was found by observing {[}13.3]4-X-3 Phi(3) and
{[}13.3]4-X-3 Phi(4) transitions in the spectrum of CoD. Analysis of the
transitions with Delta Omega = 0, +/- 1 provided more accurate values of
spin-orbit splittings between Omega = 4 and Omega = 3 components. The
around-state data for both molecules were fitted both to band-constant
and Dunham-expansion expressions, and a combined-isotopologue analysis
of the X-3 Phi(4) spin component was carried out using the data for CoH
and CoD. The tipper states Were represented by term values in these
analyses because of perturbations, but estimated band constants for them
were obtained in separate fits in which ground-state constants were held
fixed.},
DOI = {10.1016/j.jms.2006.02.011}
}