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Electrical Characterization of RF-Sputtered HfO₂ MOS Capacitors

This repository contains the M.Sc. (Electronics Science) final-year project work focused on the electrical characterization and tunneling mechanism analysis of RF-sputtered HfO₂-based MOS capacitors.

📌 Project Overview

As CMOS devices scale down, conventional SiO₂ gate dielectrics suffer from excessive leakage current due to quantum mechanical tunneling. High-k dielectrics such as HfO₂ offer improved capacitance control while reducing equivalent oxide thickness (EOT).

This project investigates the effect of RF sputtering time and post-deposition annealing temperature on the electrical behavior and tunneling mechanisms of HfO₂ MOS capacitors.

🔬 Key Objectives

  • Fabrication of HfO₂ thin films using RF magnetron sputtering
  • Electrical characterization using C–V and I–V measurements
  • Identification of dominant tunneling mechanisms (FN, PF, Schottky)
  • Analysis of interface states, oxide charge density, and leakage current behavior

🧪 Experimental Details

  • Substrate: p-type Si ⟨100⟩
  • Deposition: RF magnetron sputtering
  • Sputtering time: 5 min, 10 min, 20 min
  • Annealing: 500 °C and 600 °C (RTA in O₂)
  • Contacts: Pt/HfO₂/p-Si MOS structure

📊 Characterization Techniques

  • Spectroscopic Ellipsometry (Thickness analysis)
  • C–V and G–V Measurements (Keysight LCR Meter)
  • I–V Measurements (Keithley Source Meter)
  • Fowler–Nordheim and Poole–Frenkel fitting

📈 Key Findings

  • Film thickness increases with sputtering time
  • Annealing reduces interface trap density and oxide charge
  • Poole–Frenkel emission dominates at low electric fields
  • Fowler–Nordheim tunneling dominates at high electric fields

📂 Repository Contents

  • Theory/ – MOS physics and tunneling mechanisms
  • Fabrication/ – RF sputtering and annealing process
  • Results/ – Experimental data and analysis
  • Plots/ – Electrical characterization plots
  • Thesis/ – Complete MSc thesis (PDF)
  • Presentation/ – Project presentation slides

👨‍🔬 Authors

  • Abhijeet Singh
  • Sreemoyee Saha

🎓 Supervisor

Prof. Anupam Karmakar
Department of Electronic Science
University of Calcutta

📚 Keywords

MOS Capacitor, HfO₂, High-k Dielectrics, RF Sputtering, C–V Analysis, I–V Analysis, Fowler–Nordheim Tunneling, Poole–Frenkel Emission

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M.Sc. project on electrical characterization and tunneling mechanism analysis of RF-sputtered HfO₂ MOS capacitors using C–V and I–V measurements.

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